Product ID:BB UMBER COLORANT, 674-18
MSDS Date:03/24/1995
FSC:8010
NIIN:00N075128
MSDS Number: CCSRF

O'BRIEN CORP

450 EAST GRAND AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 415-761-2300

Cage: FO983

O'BRIEN CORP

SOUTH SAN FRANCISCO, CA 94080 US

Telephone: (415) 761-2300

Cage: FO983

0.06

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 25%

OSHA PEL N/K

ACGIH TLV: C 50 PPM, VAPOR

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

0.10

CAS: 9016-45-9

RTECS: MD0900000

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: <5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

IRON OXIDE

CAS: 1309-37-1

RTECS: NO7400000

Fraction By Weight: <5%

OSHA PEL 10 MG/M3 (FE)

ACGIH TLV: 5 MG(FE)/M3 FUME, B2

ALUMINUM SILICATE

CAS: 1302-76-7

RTECS: BD1450000

Fraction By Weight: 10%

OSHA PEL 15 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <1%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST

534.77 G/L

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

MAY BE IRRITATING. ALUMINUM

RTECS: 9999999ZZ

IRRITATING TO UPPER RESP

RTECS: 9999999ZZ

STUDIES SHOW THAT EXPOS OF PREGNANT ANIMALS TO

RTECS: 9999999ZZ

EVID EXISTS SUGGESTING THAT ETHYLENE GLYCOL HAS

RTECS: 9999999ZZ

IN 1978, NIOSH CONCLUDED THAT

RTECS: 9999999ZZ

& "MAY POSE CANCER RISK" DUE TO ABSORB POLYCYCLIC

RTECS: 9999999ZZ

INCR CIRCULATORY MALIGNANT/RESP MORBIDITY AMONG

RTECS: 9999999ZZ

PRDCE SIDEROSIS W/VISIBLE CHANGES ON CHEST X-RAY.

RTECS: 9999999ZZ

SILICA

RTECS: 9999999ZZ

SHOWN TO CAUSE SILICOSIS, A PROGRESSIVE LUNG DISEASE

RTECS: 9999999ZZ

WITH SOAP AND WATER. REMOVE CONTAMINATED

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:PRIMARY IRRIT. INHAL:MAY
CAUSE HDCH & NAUS. SKIN:POSS PRIMARY IRRIT. ETHYLENE
GLYCOL:INGEST:IRRITATING TO GI TRACT. ABDOM PAIN; DIARR; CNS
DEPRESS; MALAISE;MENTAL SLUGGISHNESS, IN SEV CASES BRTHG & HEART
FAILURE. ACUTE POISONING MAY DMG KIDNEYS, SEV CASES CAN RSLT IN
DEATH DUE TO THIS EFT. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 65, PG 24-27; 1995:GROUP 2B.
SILICA, (SUPDAT)
Effects of Overexposure:HLTH HAZ:INHAL:UPPER RESP IRRIT. HDCH, DIZZ,
NAUS, VOMIT. EYE:IRRITATING. SKIN:MAY CAUSE IRRIT.
NONYLPHENOXYPOLYETHOXYETHANOL:INGEST:MOD TOX. IRRIT OF GI TRACT IS
PROBABLE. INHAL:IRRITATING TO UPPER R ESP TRACT. COUGH & DFCLT
BRTHG. EYE:SEVIRRIT & POSS PERM DMG. SKIN:IRRIT, POSSIBLY SEV UPON
PRLNGD CONT. (SUPDAT)
Medical Cond Aggravated by Exposure:IRON OXIDE:OBTAIN MED ATTN AFTER
FIRST AID HAS BEEN GIVEN. CRYSTALLINE SILICA, AS QUARTZ:MAY
AGGRAVATE EXISTING LUNG DISEASES, A LUNG TOXIN.

First Aid:INGEST:DRINK 1-2 GLASSES OF WATER & INDUCE VOMIT BY PLACING
FINGER @ BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERSON. CONSULT PHYS/POIS CTL CTR IMMED. INHAL:REMOVE FROM AREA TO
FRESH AIR. RESTORE BRTHG. EYE:IMMED BEGIN FLUSHING W/COOL WATER,
OCCASNLY LIFTING LIDS TO ENSURE THOROUGH RINSING. CONTINUE FOR @
LST 15 MINS. WHILE FLUSHING, SEND FOR MED ASSISTANCE. SKIN:WASH
THORO (ING 18)

Flash Point:>200F,>93C
Extinguishing Media:NOT APPLICABLE. MEDIA SUITABLE FOR SURROUNDING FIRE
.
Fire Fighting Procedures:NOT APPLICABLE. USE NIOSH APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT.

Spill Release Procedures:SOAK UP AND REMOVE WITH INERT ABSORBENT
MATERIAL. PROVIDE ADEQUATE VENTILATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP FROM FREEZING. AVOID PROLONGED
CONTACT WITH SKIN. DO NOT INGEST.
Other Precautions:KEEP OUT OF THE REACH OF CHILDREN.

Respiratory Protection:USE NIOSH APPROVED MECHANICAL RESPIRATOR OR MASK
TO AVOID BREATHING SPRAY MIST.
Ventilation:PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP AIR CONTAM
CONC BELOW APPLIC OSHA PEL EXPOS LEV/ACGIH'S TLV LIMIT.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
PROTECTIVE OVERALLS RECOMMENDED. DISCARD CONTAMINATED SHOES.
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING.
Supplemental Safety and Health
EXPLAN OF CARCIN:CRYSTALLINE-QUARTZ:IARC MONOGRAPHS, SUPP. VOL 7, PG
341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE
CARCIN. EFTS OF OVEREXP:CARBON BLACK:EYE:MAY BE IRRITATING & MA Y
CAUSE CONJ. SKIN:PRLNGD/RPTD CONT MAYCAUSE IRRIT. IRON OXIDE:EXCESS
DUST LEVS MAY PRDCE NONSPECIFIC IRRIT OF (ING 8)

Boiling Pt:B.P. Text:212F,100C
Vapor Pres:SEE INGS
Vapor Density:LTR/AIR
Spec Gravity:1.48
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT KNOWN
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:65.08

Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CO, CO*2, AND NO*2.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DO NOT INCINERATE IN CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.